| Date | Location | Result | |
| Nov 29, 2012 | Sioux City, Iowa | Madonna 3, Carroll 0 (25-13,25-23,25-14) | Box score |
| Nov 28, 2012 | Sioux City, Iowa | Columbia 3, Madonna 1 (25-23,25-18,23-25,25-21) | Box score |
| Nov 27, 2012 | Sioux City, Iowa | Oklahoma Baptist 3, Madonna 1 (25-23,25-18,22-25,26-24) | Box score |
| Nov 17, 2012 | Livonia, Mich. | Madonna 3, St. Xavier 1 (25-18,25-15,23-25,25-16) | Box score |
| Nov 10, 2012 | Livonia, Mich. | Madonna 3, Davenport 0 (25-17,25-20,25-21) | Box score |
| Nov 10, 2012 | Livonia, Mich. | Madonna 3, Cornerstone 0 (25-15,27-25,25-23) | Box score |
| Nov 09, 2012 | Livonia, Mich. | Madonna 3, Siena Heights 0 (25-17,25-11,25-11) | Box score |
| Nov 02, 2012 | Adrian, Mich. | Madonna 3, Siena Heights 0 (25-17,25-18,25-23) | Box score |
| Oct 31, 2012 | Livonia, Mich. | Madonna 3, Indiana Tech 0 (25-21,25-22,25-18) | Box score |
| Oct 24, 2012 | Lima, Ohio | Northwestern Ohio 3, Madonna 1 (25-11,24-26,25-21,25-20) | Box score |
| Oct 20, 2012 | Livonia, Mich. | Madonna 3, Trinity Int'l. 0 (25-22,25-6,25-10) | Box score |
| Oct 20, 2012 | Livonia, Mich. | Madonna 3, Rochester 0 (25-10,25-17,25-22) | Box score |
| Oct 19, 2012 | Livonia, Mich. | Embry-Riddle 3, Madonna 1 (27-25,18-25,25-23,25-20) | Box score |
| Oct 19, 2012 | Livonia, Mich. | Madonna 3, Daemen 2 (25-21,24-26,25-13,22-25,15-10) | Box score |
| Oct 17, 2012 | Livonia, Mich. | Madonna 3, Lawrence Tech 0 (25-12,25-17,25-15) | Box score |
| Oct 13, 2012 | Ann Arbor, Mich. | Madonna 3, Cincinnati Christian 0 (25-12,25-15,25-17) | Box score |
| Oct 12, 2012 | Livonia, Mich. | Madonna 3, Michigan-Dearborn 1 (26-24,17-25,25-16,25-15) | Box score |
| Oct 10, 2012 | Grand Rapids, Mich. | Madonna 3, Davenport 1 (23-25,25-17,25-23,25-23) | Box score |
| Oct 06, 2012 | Fort Wayne, Ind. | Indiana-East 3, Madonna 2 (22-25,25-22,22-25,25-18,15-12) | Box score |
| Oct 06, 2012 | Fort Wayne, Ind. | Madonna 3, Ashford 0 (25-19,25-15,25-16) | Box score |
| Oct 05, 2012 | Fort Wayne, Ind. | Madonna 3, St. Ambrose 1 (25-23,27-29,25-22,25-19) | Box score |
| Oct 05, 2012 | Fort Wayne, Ind. | Madonna 3, Campbellsville 1 (26-24,25-21,22-25,30-28) | Box score |
| Oct 03, 2012 | Ann Arbor, Mich. | Madonna 3, Concordia 0 (25-13,25-19,25-22) | Box score |
| Sep 26, 2012 | Livonia, Mich. | Madonna 3, Cornerstone 0 (25-21,25-23,27-25) | Box score |
| Sep 21, 2012 | Livonia, Mich. | Madonna 3, Aquinas 0 (25-18,25-12,25-13) | Box score |
| Sep 19, 2012 | Livonia, Mich. | Madonna 3, Marygrove 0 (25-13,25-10,25-12) | Box score |
| Sep 15, 2012 | Livonia, Mich. | Madonna 3, Windsor 0 (25-14,25-14,25-16) | Box score |
| Sep 15, 2012 | Livonia, Mich. | Madonna 3, Western Ontario 0 (25-10,25-17,28-26) | Box score |
| Sep 12, 2012 | Sylvania, Ohio | Madonna 3, Lourdes 0 (25-18,25-16,25-23) | Box score |
| Sep 08, 2012 | Livonia, Mich. | Madonna 3, St. Francis (Ill.) 2 (20-25,23-25,25-21,25-15,15-13) | Box score |
| Sep 08, 2012 | Livonia, Mich. | Madonna 3, Rochester 0 (25-19,25-18,25-17) | Box score |
| Sep 07, 2012 | Livonia, Mich. | Madonna 3, Illinois Tech 0 (25-11,25-21,25-12) | Box score |
| Sep 07, 2012 | Livonia, Mich. | Madonna 3, Windsor 0 (25-19,25-5,25-14) | Box score |
| Sep 05, 2012 | Livonia, Mich. | Madonna 3, Windsor 0 (25-22,25-10,25-15) | Box score |
| Sep 01, 2012 | Daytona Beach, Fla. | Embry-Riddle 3, Madonna 0 (25-22,25-16,25-17) | Box score |
| Sep 01, 2012 | Daytona Beach, Fla. | Texas at Brownsville 3, Madonna 0 (25-17,25-19,25-22) | Box score |
| Aug 31, 2012 | Daytona Beach, Fla. | Madonna 3, Montreat 0 (25-19,25-9,25-15) | Box score |
| Aug 31, 2012 | Daytona Beach, Fla. | Oklahoma Baptist 3, Madonna 2 (20-25,25-22,25-17,20-25,15-13) | Box score |
| Aug 25, 2012 | Dearborn, Mich. | Madonna 3, Point Park 1 (19-25,27-25,25-17,25-20) | Box score |
| Aug 25, 2012 | Dearborn, Mich. | Madonna 3, St. Xavier 0 (25-17,25-11,25-20) | Box score |
| Aug 24, 2012 | Dearborn, Mich. | Madonna 3, Daemen 0 (25-18,25-21,25-17) | Box score |
| Aug 24, 2012 | Dearborn, Mich. | Georgetown 3, Madonna 2 (25-20,25-22,20-25,21-25,15-13) | Box score |
| Aug 22, 2012 | Livonia, Mich. | Madonna 3, Spring Arbor 0 (25-18,25-19,25-19) | Box score |
| Aug 21, 2012 | Livonia, Mich. | Madonna 3, St. Francis (Ind.) 1 (25-15,21-25,25-13,25-20) | Box score |